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Andrussow process : ウィキペディア英語版
Andrussow process

The Andrussow process is an industrial process for the production of hydrogen cyanide from methane and ammonia in the presence of oxygen and a platinum catalyst.
:CH4 + NH3 + 1.5 O2 → HCN + 3 H2O
==Side Reactions==
This reaction is very exothermic. The change of enthalpy of this reaction is equal to ''-481.06 kJ''. The heat provided by the main reaction serves as a catalyst for other side reactions.
:CH4 + H2O → CO + 3 H2
:2 CH4 + 3 O2 → 2 CO + 4 H2O
:4 NH3 + 3 O2 → 2 N2 + 6 H2O
These side reactions can be reduced by only short exposures to the catalyst of the order of 0.0003s.
The process is based on a reaction that was discovered by Leonid Andrussow in 1927. In the following years he developed the process that is named after him. HCN is also produced in the BMA process.

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